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Molecular shape, form, and symmetry play a central role in organic chemistry, and this text presents a brief introduction to the conceptual basis of stereochemistry. Its focus lies in the fundamentals of structural stereochemistry, rather than the dynamic aspects that are more relevant to reaction mechanisms. The three-part treatment deals with structure and symmetry, stereoisomerism, and the separation and configuration of stereoisomers. The first...
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Concise explanation of the logical development of basic crystallographic concepts. Extensive discussion of crystals and lattices, symmetry, crystal systems and geometry, x-ray diffraction, determination of atomic positions, and more. Well-chosen selection of problems, with answers. Ideal for crystallography course or as supplement to physical chemistry courses. 114 illustrations. 1969 edition.
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This profile of the evolution of the "spin" concept from its role in quantum mechanics to its assimilation into the field of chemistry examines spin and valence, spin Hamiltonians, nuclear hyperfine effects and electron spin-spin coupling, the g tensor, and nuclear spin-spin coupling. 16 figures. 1970 edition.
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This graduate-level text develops the aspects of group theory most relevant to physics and chemistry (such as the theory of representations) and illustrates their applications to quantum mechanics. The first five chapters focus chiefly on the introduction of methods, illustrated by physical examples, and the final three chapters offer a systematic treatment of the quantum theory of atoms, molecules, and solids. The formal theory of finite groups and...
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This rich record of the major interests of Paracelsus and other 16th-century chemical philosophers covers chemistry and nature in the Renaissance, Paracelsian debates, theories of Fludd, Helmontian restatement of chemical philosophy, and other fascinating aspects of the era. Well researched, compellingly related study. 36 black-and-white illustrations.
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Intended for graduate and advanced undergraduate students, this text explores quantum mechanical techniques from the viewpoint of chemistry and materials science. Dynamics, symmetry, and formalism are emphasized. An initial review of basic concepts from introductory quantum mechanics is followed by chapters examining symmetry, rotations, and angular momentum addition. Chapter 4 introduces the basic formalism of time-dependent quantum mechanics, emphasizing...
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Concise, self-contained introduction to group theory and its applications to chemical problems. Symmetry, symmetry operations, point groups, matrices, matrix representations, equivalent and reducible representations, irreducible representations and character tables, representations and quantum mechanics, molecular vibrations, molecular orbital theory, hybrid orbitals, and transition metal chemistry. Advanced-undergraduate/graduate level.
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This guide is guaranteed to prove of keen interest to the broad spectrum of experimental chemists who use electronic structure theory to assist in the interpretation of their laboratory findings. A list of 150 landmark papers in ab initio molecular electronic structure methods, it features the first page of each paper (which usually encompasses the abstract and introduction). Its primary focus is methodology, rather than the examination of particular...
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This authoritative test introduces the basic aspects of diffusion phenomena and their methods of solution through physical examples. It emphasizes modeling and methodology, bridging the gap between physico-chemical statements of certain kinetic processes and their reduction to diffusion problems. Author Richard Ghez draws upon his experience in the areas of metallurgy and semiconductor technology to present physically significant examples that will...
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This systematic approach to the quantum theory of collective phenomena is based principally on the model of infinite systems. Suitable for advanced undergraduates and graduate students of physics and chemistry, the three-part treatment begins with an exposition of the generalized form of quantum theory of both finite and infinite systems. Part II consists of a general formulation of statistical thermodynamics, and the final part provides a treatment...
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